Stereochemistry of post-transition metal oxides: revision of the classical lone pair model
نویسندگان
چکیده
منابع مشابه
Stereochemistry of post-transition metal oxides: revision of the classical lone pair model.
The chemistry of post transition metals is dominated by the group oxidation state N and a lower N-2 oxidation state, which is associated with occupation of a metal s(2) lone pair, as found in compounds of Tl(I), Pb(II) and Bi(III). The preference of these cations for non-centrosymmetric coordination environments has previously been rationalised in terms of direct hybridisation of metal s and p ...
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ژورنال
عنوان ژورنال: Chemical Society Reviews
سال: 2011
ISSN: 0306-0012,1460-4744
DOI: 10.1039/c1cs15098g